This is another excellent question I usually get.
The answer is, YES.
Yes, you can connect your payoneer card in the paypal account you created. Make sure that your payoneer card balance has at least 5 USD in it.
But, unfortunately you might not be able to add your USA bank account from Payoneer in your paypal anymore.
PayPal stopped recognizing the virtual USA bank account from payoneer.
*** Those who have old bank account from payoneer can still use their account with PayPal. Do not disconnect it otherwise you might not be able to add it again.